Org KEM030

The exercise was created 2024-09-09 by glarboo. Question count: 168.

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  • Ge namn för: Alken + 1. Hg(OAc)2 H2O/THF 2. NaBH4 = alcohol Oxymercuration-demercuration, Hydroboration-oxidation, Catalytic hydrogenation
  • Sker markovnikov regiokemi i: Alken + 1. Hg(OAc)2 H2O/THF 2. NaBH4 Ja, Nej
  • Alken + 1. Hg(OAc)2 + H2O/THF 2. NaBH4 = ? Alcohol, Ketone, Ester
  • Alken + 1.BH3 2. H2O2 OH- = ? Alcohol, Ketone, Ester
  • Alken + 1.BH3 2. H2O2 OH- Non-markovnikov, Markovnikov
  • Alken + 1.BH3 2. H2O2 OH- har vad för reaktionsnamn? Hydroboration-oxidation
  • Alken + H2 Pd/C or PtO2 = ? Alkan, Alkyn, Alcohol
  • Alken + H2 Pd/C or PtO2 Syn, Anti-syn
  • Namn för reaktionen av Alken + H2 Pd/C or PtO2 Catalytic hydrogenation
  • Alken + 1. OsO4 2. NaHSO3 H2O or OsO4 NMO Cis diol, Trans diol, Mono alcohol
  • Alken + 1. OsO4 2. NaHSO3 H2O or OsO4 NMO Hydroxylation, Epoxification, Addition
  • Alken + CHCl3 + KOH Diclorocyclopropane, Ester, Dicloropropane
  • Alkene + CHCl3 + KOH Dichlorocarbene addition, Simmons-smith reaction, Catalytic hydrogenation
  • Alkene + CH2I2 + Zn(Cu) Cyclopropane, Alkane, Alkyn
  • Alkene + CH2I2 + Zn(Cu) Simmons-smith reaction, Dichlorocarbene addition, Epoxification
  • Alkene + 1. O3 2. Zn/H3O+ Two ketones, Epoxy, Ester
  • Alkene + 1. O3 2. Zn/H3O+ Oxidative cleavage, Hydroxylation, addition reaction
  • (R)2CC(R)2 + KMnO4 H3O+ Two ketones, Carboxylic acid, Ester
  • RC=C + KMnO4 H3O+ Carboxylic acid + CO2, Two ketones, Ester
  • Diolalkane + HIO4 H2O Two ketones, Alkene, Epoxy
  • 1 2-Dibromoalkane (Cis) + 2 KOH or NaNH2 NH3 Alkyne + 2 H2O + 2 KBr, Alkene, Epoxy
  • 1 2-Dibromoalkane + 2 KOH or NaNH2 NH3 Dehydrohalogenation, Epoxyfication, Alkylation
  • Bromoalkene (Hydrogen cis with bromo) + KOH or NaNH3 NH3 Alkyn + H2O + KBr, Epoxy, Two Ketones
  • Etyne + 1. NaNH2 2. RCH2Br Terminal alkyne, Internal alkyne, Anhydride
  • Etyne + 1. NaNH2 2. RCH2Br Alkylation, epoxification, hydration
  • Etyn + 2 HX 1 2-Dihaloethene (trans), 1 2-Dihaloethane (Cis), Haloethene
  • RCCH + H2SO4 H2O HgSO4 Methyl ketone, Ketone, Ester
  • RCCH + H2SO4 H2O HgSO4 Hydration, Reduction, Addition
  • internal alkyne + 1. BH3 2. H2O2 + H2O + NaOH Ketone, Alkene, Aldehyde
  • Terminal alkyne + 1. BH3 2. H2O2 + H2O Aldehyde, Ketone, Alkene
  • Alkyne + 2H2 Pd/C Alkane, Alkene, Ketone
  • Alkyne + 2H2 Pd/C Catalytic hydrogenation, Addition, Hydroboration-oxidation
  • Alkene + H2 + Lindlar catalyst Cis alkane, Cis alkene, Aldehyde
  • Alkene + H2 + Lindlar catalyst Catalytic hydrogenation, Addition, Hydration
  • Alkene + Li + NH3 Trans alkene, Cis alkene, Alkane
  • RCCH + NaNH2 + NH3 Acetylide anion + NH3, Ketone, Aldehyde + NH3
  • C=C–C Allyl, Aryl, Acetyl
  • 3-Hydroallyl (no other hydrogens attached) + NBS hv CCl4 3-Bromoallyl, 2-Bromoallyl, Ketone
  • 3-Hydroallyl (no other hydrogens attached) + NBS hv CCl4 Allylic bromination, Addition, Hydration
  • 1° and 2° alcoholes + SOCl2 1° or 2° Cl-C, Dichloroalkane, Alkyn
  • 1° or 2° alcohol + PBr3 1° or 2° Br-C, Alkyn, Tribromoalkane
  • RX + 2Li RLi + LiX, R(Li)X + HLi
  • 2 RLi + CuI [R-Cu-R]- + Li+ + LiI, Something else
  • [R-Cu-R]- Li+ Gilman reagent, Grignard reagent
  • R2CuLi + R'X RR' + RCu + LiX, something else
  • R2CuLi + R'X Diorganocopper reaction, Gilman reagent
  • Draw palladium-catalysed Suzuki-Miyaura reaction Yer, Ner
  • Monohaloalkane + base E1cB reaction, E1 reaction, Sn1 reaction
  • 1 3-Buta-di-ene + HBr 3-Bromo-1-Butene (MAJOR) or 1-Bromo-2-butene, Something else
  • 1 3-Butadiene + 3-Buten-2-one + Heat 3-Cyclohexenyl methyl ketone, ERROR
  • 1 3-Butadiene + 3-Buten-2-one + Heat name for reaction Diels-adler cycloaddition
  • Benzene + F-TEDA-BF4 Fluorobenzene, Bromobenzene, Hexatriene
  • Benzene + F-TEDA-BF4 Substitution reaction, Addition reaction
  • Benzene + Br2 + FeBr3 Bromobenzene + HBr, Bromobenzene + 2Hbr, Bromobenzene
  • Benzene + Cl2 + FeCl3 Chlorobenzene + HCl, Chlorobenzene + 2HCl, Chlorobenzene
  • Benzene + I2 + CuCl2 Iodobenzene + HI, Iodobenzene + 2HI, Iodobenzene
  • Benzene + I2 + ? = Iodobenzene + IH CuCl2, FeI3, FeCl2, FeCl3, CuCl3
  • Benzene + SO3 + H2SO4 Benzenesulfonic acid, Sulfobenzene, Phenol
  • Benzene + SO3 + H2SO4. Name the product Benzenesulfonic acid
  • Benzene + CH3Cl AlCl3 Toluene + HCl, Chlorobenzene + H2, Dichlorobenzene
  • Benzene + CH3Cl AlCl3 Friedel-Crafts alkylation, Toluenation, Nucleophilic aromatic substitution
  • Benzene + Ethanoyl chloride AlCl3 1-Phenylethan-1-one + HCl, Benzoic acid + HCl
  • Benzene + Ethanoyl chloride AlCl3 Friedel-Crafts acylation, Friedel-Crafts alkylation
  • Nitrobenzene + 1. Fe H3O+ 2. HO- Aniline, Pyridine, Benzaldehyde
  • 2-Chloro-1 3 5-trinitrobenzene + NA+ -OH H2O 2 4 6-trinitrophenol + NaCl, 1-Hydroxy-2 4 6-trinitrobenzene
  • Bromobenzene + Na+ -NH2 NH3 Aniline + NaBr, Benzoic acid, Hexadiene + NaBr
  • Toluene + NBS (BzO)2 CCl4 (bromomethyl)benzene, Benzoic acid, Toluene
  • Benzene + H2 Rh/C catalyst Cyclohexane, Hexane, Hexene
  • Benzene + H2 Rh/C catalyst Catalytic hydrogenation, Oxidation, Friedel-Crafts
  • Aryl alkyl ketone + H2/Pd Aryl alkyl, Aryl alkyl hydroxide, Aryl
  • 1.−CH=CH2 2.H2C=CH2 3. R attached to aromatic ring 1.Allyl 2.Vinyl 3.Aryl, 1.Vinyl 2.Aryl 3.Allyl, 1.Aryl 2.Vinyl 3.Allyl
  • Ethanol + POCl3 Alken, Alkyn, Alkan, Chloroethane
  • NBS has what name? n-bromosuccinimide
  • Reagents for Phenols to quinones (? + ?) Na2Cr2O7 + H2O
  • Quinones are what? Aromatic compound with an even number of -CH= converted to -C(=O)-, Aromatic compound with -CH= converted to -C(=O)-
  • RO- + R'CH2X ROCH2R' + X-, ROR'CH3 + X-, R'RC(O)OH + HCl
  • Name of reaction RO- + R'CH2X Williamson ether synthesis
  • Alkene + 1. ROH (CF3CO2)2Hg 2. NaBH4 Ether (Cis with hydrogen), Ether (Trans with hydrogen)
  • Alkene + 1. ROH ? 2. NaBH4 (CF3CO2)2Hg
  • Alkene + 1. ? (CF3CO2)2Hg 2. NaBH4 ROH
  • Alkene + 1. ROH (CF3CO2)2Hg 2. ? NaBH4
  • Alkene + 1. ROH (CF3CO2)2Hg 2. NaBH4 Alkoxymercuration/demercuration, Williamson ether synthesis, Claisen rearrangement
  • ROR' + HX H2O RX + R'OH, Something else lol
  • Allyl phenyl ether + 250°C o-Allylphenol, m-Allylphenol, p-Allylphenol
  • Allyl phenyl ether + 250°C undergoes what process? Claisen rearrangement
  • RCH2Br + 1. (H2N)2C=S 2. H2O NaOH RCH2SH, RCHN + SH2
  • 2RSH + I2 H2O RSSR, RSRS, ROSRSH
  • RS- + R'CH2Br RSCH2R' + Br-, IDK IDC
  • RSR' + H2O2 RS(O)R, RSOOR
  • R'SR' + RCO3H R'SOOR', R'S(O)R'
  • Alkoyl chloride + R'2CuLi RCOR', R'COR'
  • Ketone + HCN Cyanohydrin, 2° Alcohol, Cyanoalkane
  • Ketone + primary amine Imine + H2O, Nitrile + H2O, Secondary amine
  • ketone + Secondary amine Enamine + H2O, Tvåamine + H2O, Secondary amine + H2O
  • Ketone + H2NNH2 KOH Alkan + N2 + H2O, Alkan + N2, Alkan + H2O
  • Ketone + 2 ROH + Acid catalyst Diol + H2O, Alcohol + H2O, Ester + H2O
  • Ketone + (C6H5)3PCHR Alkene + (C6H5)3P=O, Alkane + (C6H5)2P=O
  • Name for reaction of Ketone + (C6H5)3PCHR Wittig reaction
  • RCOC=C + 1. R'2CuLi 2. H3O+ RCOCCR', something else
  • Name of reaction RCOC=C + 1. R'2CuLi 2. H3O+ Diorganocopper reaction
  • Amide + SOCl2 RCN + SO2 + 2 HCl, RCOCl + SOCl-
  • Nitrile + 1. NaOH H2O 2. H3O+ Carboxyl + NH3, Ester + NH3, Primary amine
  • Carboxyl + RNH2 DCC Secondary amide, Primary amide, tertiary amide
  • alkanoic halide + RCO2- Anhydride, Aldehyde, Ester
  • Alkanoic halide + 2NH3 Primary amide + NH4Cl, Primary amine + NH2Cl + H2O
  • Alkanoic halide + R2CuLi Ketone, Aldehyde, Ester
  • Anhydride + H2O 2 Carboxylic acids, 2 Esters, Aldehyde and Carboxylic acid
  • Anhydride + ROH Ester and Carboxylic acid, 2 Carboxylic acids, 2 Esters
  • Anhydride + 2 NH3 Primary amide + RCOO-+NH4, 2 Amides
  • Aldehyde/ketone (with at least one hydrogen present) + X2 CH3CO2H Mono-halogenated ketone/aldehyde, Haloalkane + OH-
  • Carboxylic acid (hydrogen on C2) + 1. Br2 + PBr3 2. H2O 2-Bromoalkanoic acid, 2-Alkenoic acid
  • Name for Carboxylic acid (hydrogen on C2) + 1. Br2 + PBr3 2. H2O Hell-Volhard-Zelinskii bromination
  • Alpha-bromo ketone + pyridine + heat Alkenon, Bromoalkane, Alkanon
  • RCOMe + X2 NaOH RCOO- + CHX3, RCOO- + CHX2 + HCl
  • EtO2CCH2CO2Et + 1. Na+-OEt 2. RX EtO2CCHRCO2Et, EtO2CCHRCO2
  • EtO2CCHRCO2Et + H3O+ + Heat RCH2COOH (Carboxylic acid) + CO2 + 2EtOH, Ester, CH2COOR (Ester) + CO2 + 2EtOH
  • EtO2CCH2CO2Et --> Carboxylic acid + CO2 + 2 EtOH. What synthesis is this? Masonic ester synthesis
  • EtO2CCH2COCH3 + 1. Na+-OEt 2. RX EtO2CCHRCOCH3, EtO2CCHRCOOCH3
  • EtO2CCHRCOCH3 + H3O+ + Heat Ketone + CO2 + EtOH, Ester + CO2 + EtOH
  • Ketone (H on C2) + 1. LDA in THF 2. RX A longer ketone, Ester, Carboxylic acid
  • Ester (H by =O) + 1. LDA in THF 2. RX A longer ester, Ketone, Carboxylic acid
  • Nitrile (H on C2) + 1. LDA in THF 2. RX A longer nitrile, Ester, Primary amine
  • Draw an aldol reaction Drew correctly, Drew incorrectly
  • Draw two mixed aldol reactions Drew correctly, Drew incorrectly
  • Draw an intramolecular aldol reaction Drew correctly, Drew incorrectly
  • Draw a dehydration of an aldol product Drew correctly, Drew incorrectly
  • Draw Claisen condensation reaction Drew correctly, Drew incorrectly
  • Draw a mixed Claisen condensation reaction Drew correctly, Drew incorrectly
  • Draw an intermolecular Claisen condensation reaction Drew correctly, Drew incorrectly
  • Draw a Michael reaction Drew correctly, Drew incorrectly
  • Draw and somehow understand the Stork reaction Drew correctly?, Drew incorrectly?
  • RCH2X + NaCN Nitrile, Primary amine, Alkane
  • Nitrobenzene + H2 Pt Aniline, No reaction occurs
  • Nitrobenzene + Fe H3O+ Aniline, No reaction occurs
  • Nitrobenzene + SnCl2 H3O+ Aniline, No reaction occurs
  • Nitrobenzene + Cu + H3O+ No reaction occurs, Aniline
  • Nitrobenzene + SnCl3 + H3O+ No reaction occurs, Aniline
  • NH3 + RX + NaOH Primary amine, Secondary amine, Tertiary amine
  • R3N + RX Quaternary ammonium, No reaction occurs
  • Draw Gabriel amine synthesis Drew correctly, Drew incorrectly
  • RCH2X + Na+-N3 RCH2NNN, RCH+ + NaX N3
  • RCH2NNN + 1. LiAlH4 2. H2O Primary amine, Secondary amine, Tertiary amine
  • Primary amide + NaOH + Br2 + H2O Primary amine + CO2, Secondary amine + CO2, Tertiary amine + CO2
  • Alkanoic chloride + Na+-N3 RCONNN, Something else oof
  • Draw a Curtius rearrangement of acyl azides I done did it right, I Dag nabit screwed myself
  • Tertiary amine (Trans with a hydrogen) + 1. CH3I 2. Ag2O + Heat Alkene, Ketone, Secondary amine
  • Aniline + HNO2 + H2SO4 Ph-N(+)N + HSO4-, Benzene, Benzoic acid
  • What is this process called: Aniline + HNO2 + H2SO4 Diazotization
  • Draw the 6 possible Nucleophilic substitutions (and their reagents) for Ph-NN + HSO4- Drew em, Would like to try again
  • Draw two diazonium couplings (one with phenol on with Ph-NR2) DID IT, DID NOT DID IT
  • From chapter 26: Form alpha-promo acids Y, N
  • From chapter 26: Diethyl acetamidomalonate synthesis Y, N
  • From chapter 26: Reductive amination of an alpha-veto acid Y, N
  • From chapter 26: Enatioselective synthesis Y, N
  • From chapter 26: Peptide sequencing by Edman degradation Y, N
  • From chapter 26: Amine to Boc-protected amino acid Y, N
  • From chapter 26: Carbonyl protection (Two ways) Y, N
  • From chapter 29: Mechanism for the action of Lipase Y, N
  • From chapter 29: The four steps of the ß-oxidation pathway Y, N
  • From chapter 29: Acetyl CoA to Butyryl ACP Y, N
  • From chapter 29: Mechanism for step three in Acetyl CoA to Butyryl ACP Y, N
  • From chapter 29: Ten-step glycolysis pathway Y, N
  • From chapter 29: Pyruvate to Acetyl CoA Y, N
  • From chapter 29: Citric acid cycle Y, N
  • From chapter 29: Glucogenesis pathway Y, N
  • From chapter 29: Mechanism for PLP-dependent transmission of alpha-amino acid to give a alpha-veto acid Y, N
  • Name for CH2 Carbene
  • Draw acetyl Drew it, Drewn't it

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